143713-49-9Relevant academic research and scientific papers
Direct hydroperoxygenation of conjugated olefins catalyzed by cobalt(II) porphyrin
Sugamoto, Kazuhiro,Matsushita, Yoh-Ichi,Matsui, Takanao
, p. 3989 - 3998 (2007/10/03)
A novel and direct synthesis of hydroperoxy compounds from various types of conjugated olefins was established via cobalt(II) porphyrin-catalyzed hydroperoxygenation. The reaction of α,β,γ,δ-unsaturated carbonyl compounds, acrylic esters, α-substituted acrylic esters and styrene derivatives with molecular oxygen and triethylsilane in the presence of a catalytic amount of cobalt(II) porphyrin proceeded rapidly to give the corresponding hydroperoxygenated compounds in high or moderate yields.
Cobalt(II) Porphyrin-Catalyzed Oxidation of Olefins to Ketones with Molecular Oxygen and Triethylsilane in 2-Propanol
Matsushita, Yoh-ichi,Matsui, Takanao,Sugamoto, Kazuhiro
, p. 1381 - 1384 (2007/10/02)
An efficient conversion of olefins to ketones was achieved by the use of molecular oxygen and triethylsilane in the presence of a catalytic amount of cobalt(II) complex of porphyrin.The oxidation was accelerated remarkably in alcohols and had chomoselectivity for conjugated olefins.
