1437311-30-2

Basic information

• Product Name: C₂₂H₃₇NS
• Synonyms: C₂₂H₃₇NS
• CAS NO: 1437311-30-2
• Molecular Weight: 347.608
• Mol File: 1437311-30-2.mol

Chemical Properties

• CAS DataBase Reference: C₂₂H₃₇NS(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₃₇NS(1437311-30-2)
• EPA Substance Registry System: C₂₂H₃₇NS(1437311-30-2)

Safety Data

• Hazardous Substances Data: 1437311-30-2(Hazardous Substances Data)

Upstream product

• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 125188-67-2 N,N-dimethyl decanethioamide 

Relevant articles and documents

Pd-catalyzed α-arylation of thioamides

Thioamides are unique and versatile synthetic building blocks with S, N, and α-C three adjacent nucleophile centers, however, they are rarely used as carbon nucleophiles for transition-metal-catalyzed C-C coupling reactions. This Letter describes the first Pd-catalyzed α-arylation of thioamides and demonstrated the feasibility of the application of thioamides in coupling chemistry. By the coupling process, a variety of α-arylated thioamides were prepared in moderate to good yields under mild reaction conditions, which provides an alternative way to access functionalized thioamides as well as a new synthetic transformation for thioamides. High chemoselectivity for thioamide over amide was observed in the reaction.