14374-49-3Relevant academic research and scientific papers
Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes
Yang, Hongxuan,Dong, Wenke,Wang, Wencan,Li, Tao,Zhao, Wanxiang
supporting information, p. 2833 - 2840 (2020/10/06)
A new efficient method for the synthesis of a high ratio of E -alkenes from E / Z mixtures of alkenes with B 2pin 2in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.
Regio- and Enantioselective Copper-Catalyzed Allylic Alkylation of Ortho-Substituted Cinnamyl Bromides with Grignard Reagents
Van Der Molen, Nathalie C.,Tiemersma-Wegman, Theodora D.,Fa?anás-Mastral, Martín,Feringa, Ben L.
, p. 4981 - 4984 (2015/05/27)
A highly efficient method for the copper-catalyzed asymmetric allylic alkylation of ortho-substituted cinnamyl bromides with Grignard reagents is reported. The use of a catalytic system comprising CuBr·SMe2 and TaniaPhos as chiral ligands gives
REDUCTIVE TRANSFORMATIONS WITH TRIMETHYLSILYL CHLORIDE-SODIUM IODIDE. A NEW SYNTHESIS OF 4H-1,3-OXAZINES
Ghera, Eugene,Maurya, Rakesh,Hassner, Alfred
, p. 4741 - 4744 (2007/10/02)
1-Arylalkenes and 1-arylalkanols are reduced to arylalkanes on heating with trimethylsilyl chloride/sodium iodide in CH3CN.Under similar conditions enones, dialkylated in the β-position of the double bond, give 4H-1,3-oxazines.
