14376-86-4Relevant academic research and scientific papers
Lewis Acid-Catalyzed [3+2] Cycloaddition of Donor-Acceptor Cyclopropanes and Enamines: Enantioselective Synthesis of Nitrogen-Functionalized Cyclopentane Derivatives
Verma, Kamal,Banerjee, Prabal
, p. 2053 - 2058 (2016)
A straightforward and efficient method for the synthesis of nitrogen-functionalized cyclopentane derivatives via [3+2] cycloaddition of enamines with donor-acceptor cyclopropanes in the presence of catalytic amounts of various Lewis acids at room temperat
An unusual Michael addition-dealkylation or elimination via the reaction of tertiary or secondary amines with a (Z)-iodoacrylate
Maw, Graham,Thirsk, Carl,Whiting, Andrew
, p. 8387 - 8390 (2001)
A series of (E)-ammonium or amino acrylates have been prepared via the Michael addition of methyl (Z)-iodoacrylate and several secondary and tertiary alkylamines. Tertiary amines undergo concomitant addition-dealkylation, almost quantitatively producing (
α,β-Dehydrogenation of esters with free O–H and N–H functionalities via allyl-palladium catalysis
Szewczyk, Suzanne M.,Zhao, Yizhou,Sakai, Holt A.,Dube, Pascal,Newhouse, Timothy R.
, p. 3293 - 3300 (2018/03/21)
A direct and selective method for the α,β-dehydrogenation of esters using palladium catalysis in the presence of free O–H and N–H functionalities is reported herein. Allyl-palladium catalysis allows for preservation of readily oxidizable functionalities s
