143772-59-2Relevant academic research and scientific papers
Rearrangements of the C/D Ring System of the Tetracyclic Diterpenoid, Aphidicolin
Hanson, James R.,Hitchcock, Peter B.,Jarvis, Andrew G.,Ratcliffe, Arnold H.
, p. 1773 - 1778 (2007/10/02)
The generation of a C-16 carbocation in the aphidicolane series by the hydrolysis of a 15β,16β- or a 16β,17-epoxide is shown to lead, inter alia, to skeletal rearrangement products arising from the migration of the C(12)-C(13) bond to C-16.
