143800-08-2Relevant articles and documents
(2S,3S)-2,3-Epoxy-3-trimethylsilylpropanal as a New Conjunctive Reagent
Urabe, Hirokazu,Matsuka, Tetsuji,Sato, Fumie
, p. 4179 - 4182 (2007/10/02)
The title epoxy aldehyde (>98percent ee) has been prepared.Its reactions with nucleophiles afforded the corresponding adducts with a diastereoselectivity up to 86:14.Synthetic versatility of the chiral epoxy silane moiety makes this aldehyde a useful conjunctive reagent.