1438279-73-2

Basic information

• Product Name: (2S,3R,4R)-2-(pentyloxy)-1-tosylpyrrolidine-3,4-diol
• Synonyms: (2S,3R,4R)-2-(pentyloxy)-1-tosylpyrrolidine-3,4-diol
• CAS NO: 1438279-73-2
• Molecular Weight: 343.444
• Mol File: 1438279-73-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2S,3R,4R)-2-(pentyloxy)-1-tosylpyrrolidine-3,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4R)-2-(pentyloxy)-1-tosylpyrrolidine-3,4-diol(1438279-73-2)
• EPA Substance Registry System: (2S,3R,4R)-2-(pentyloxy)-1-tosylpyrrolidine-3,4-diol(1438279-73-2)

Safety Data

• Hazardous Substances Data: 1438279-73-2(Hazardous Substances Data)

Upstream product

• 166319-26-2 1-(propa-1,2-dien-1-yloxy)pentane 
• 50487-71-3 4-methyl-N-(2-propenyl)benzenesulfonamide 
• 1438279-61-8 (S)-N-allyl-4-methyl-N-(1-(pentyloxy)allyl)benzenesulfonamide 
• 1438279-62-9 (S)-2-(pentyloxy)-1-tosyl-2,5-dihydro-1H-pyrrole 

Relevant articles and documents

A concise synthetic method towards (-)-swainsonine and its 8-epimer by using palladium-catalyzed asymmetric hydroamination of alkoxyallene as the key strategy

Abstract A concise and flexible formal synthesis of (-)-swainsonine and the 8-epimer is reported. The synthesis features sequential Pd-catalyzed asymmetric hydroamination of alkoxyallene and the Ru-catalyzed ring-closing-metathesis as the key strategy, which generates cyclic allylic N,O-acetal as the pivotal intermediate. Notably, this reaction could be performed on a multigram-scale. In addition, both the natural product and its 8-epimer could be obtained with comparable synthetic efficiency.

Synthetic strategy for cyclic amines: A stereodefined cyclic N,O-acetal as a stereocontrol and diversity-generating element

In control: A new synthetic strategy towards cyclic amines was developed and exploits a stereodefined cyclic N,O-acetal as the key stereocontrol and diversity-generating element. The cyclic N,O-acetal was prepared from the sequential asymmetric hydroamina