143838-44-2Relevant articles and documents
Rational design of CH/π interaction sites in a basic resolving agent
Kobayashi, Yuka,Kurasawa, Toshie,Kinbara, Kazushi,Saigo, Kazuhiko
, p. 7436 - 7441 (2007/10/03)
A novel synthetic basic resolving agent, cis-1-aminobenz[f]indan-2-ol (ABI), was rationally designed by introducing effective CH/π interaction sites to cis-1-aminoindan-2-ol (AI), whose chiral recognition ability has been reported from our laboratory. ABI was applicable to a wide variety of racemic arylalkanoic acids and showed moderate to excellent chiral recognition ability, which was obviously higher than that of AI. The fundamental and important role of CH/π interactions, such as tunable CH(sp2)/π and CH(sp 3)/π interactions, in the chiral recognition by ABI was revealed by X-ray crystallographic study.
Pyrrolizidine alkaloids. The synthesis and absolute configuration of all stereoisomers of 4-carboxy-4-ethyl-3-hydroxy-2-isopropyl-4-butanolide, the necic acid component of axillaridine
Matsumoto,Terao,Ishizuka,Usui,Nozaki
, p. 1761 - 1770 (2007/10/02)
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