1438414-75-5Relevant academic research and scientific papers
Aminofluorination of 2-alkynylanilines: A Au-catalyzed entry to fluorinated indoles
Arcadi, Antonio,Pietropaolo, Emanuela,Alvino, Antonello,Michelet, Veronique
, p. 449 - 458 (2014/03/21)
The scope and limitations of gold-catalyzed tandem cycloisomerization/ fluorination reactions of unprotected 2-alkynylanilines to have access to 3,3-difluoro-2-aryl-3H-indoles and 3-fluoro-2-arylindoles are described. An unprecedented aminoauration/oxidation/ fluorination cascade reaction of 2-alkynylanilines bearing a linear alkyl group on the terminal triple bond is reported.
Silver-catalyzed one-pot cyclization/fluorination of 2-alkynylanilines: Highly efficient synthesis of structurally diverse fluorinated indole derivatives
Yang, Lei,Ma, Yuanhong,Song, Feijie,You, Jingsong
supporting information, p. 3024 - 3026 (2014/03/21)
Highly efficient approaches to obtain structurally diverse fluorinated indole derivatives have been realized through the Ag-catalyzed one-pot cyclization/fluorination of 2-alkynylanilines in the presence of NFSI or Selectfluor. The Royal Society of Chemistry.
One-pot gold-catalyzed aminofluorination of unprotected 2-alkynylanilines
Arcadi, Antonio,Pietropaolo, Emanuela,Alvino, Antonello,Michelet, Véronique
supporting information, p. 2766 - 2769 (2013/07/19)
A tandem gold(I)-catalyzed aminocylization/fluorination and a two-step, one-pot gold(III)-catalyzed cyclization/electrophilic fluorination provide a convenient and general method for the synthesis of 3,3-difluoro-2-substituted- 3H-indoles in good yield un
