143850-71-9

Basic information

• Product Name: 2,2,4,4,6,6-hexanitrotricyclo[3.3.1.1~3,7~]decane
• Synonyms: 143850-71-9; 2,2,4,4,6,6-Hexanitrotricyclo[3.3.1.1(3,7)]decane; HNAD; L66 B6/B-H/DI A B- C 1B ITJ BNW BNW DNW DNW FNW FNW; Tricyclo[3.3.1.1(3,7)]decane, 2,2,4,4,6,6-hexanitro-
• CAS NO: 143850-71-9
• Molecular Formula: C₁₀H₁₀N₆O₁₂
• Molecular Weight: 406.2194
• Mol File: 143850-71-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 724.223°C at 760 mmHg
• Flash Point: 374.674°C
• Density: 1.908g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.658
• CAS DataBase Reference: 2,2,4,4,6,6-hexanitrotricyclo[3.3.1.1~3,7~]decane(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,4,4,6,6-hexanitrotricyclo[3.3.1.1~3,7~]decane(143850-71-9)
• EPA Substance Registry System: 2,2,4,4,6,6-hexanitrotricyclo[3.3.1.1~3,7~]decane(143850-71-9)

Safety Data

• Hazardous Substances Data: 143850-71-9(Hazardous Substances Data)

Upstream product

• 27871-12-1 4-hydroxyadamantane-2,6-dione 
• 143824-64-0 2,2,6,6-bis(ethylenedioxy)adamantan-4-one 
• 143824-63-9 2,2,6,6-bis(ethylenedioxy)-4-methyleneadamantane 
• 6015-40-3 4-methyleneadamantane-2,6-dione 
• 16473-11-3 bicyclo[3.3.1]nonane-2,6-dione 
• 143824-68-4 4,4,6,6-tetranitroadamantan-2-one 
• 143824-67-3 2,6-bis(hydroxyimino)-4,4-dinitroadamantane 
• 143824-66-2 4,4-dinitroadamantane-2,6-dione 
• 143824-65-1 2,2,6,6-bis(ethylenedioxy)-4-(hydroxyimino)adamantane 

Relevant articles and documents

An efficient process for the synthesis of gem-dinitro compounds under high steric hindrance by nitrosation and oxidation of secondary nitroalkanes

A new nitrosation and oxidation process to synthesize gem-dinitro compounds was accomplished by using nitryl chloride as nitrosation reagent and ozone as oxidizing agent. The main features of the present protocol include the compatibility to substances with high steric hindrance, high yields and mild reaction conditions. A plausible mechanism involving the formation of an intermediate of gem-nitrosonitro compound by means of single electron transfer was also proposed.

The Synthesis and Complete 1H and 13C NMR Spectral Assignment of 2,2,4,4,6,6-Hexanitroadamantane and its Precursor Nitroketones by 2D NMR Spectroscopy

The synthesis of 2,2,4,4,6,6-hexanitroadamantane from the precursors 4,4,6,6-tetranitroadamantan-2-one and 4,4-dinitroadamantane-2,6-dione is reported.The complete 1H and 13C NMR assignment of these compounds by 2D 13C-1H shift correlated spectra. 1H-1H COSY spectra and 1H-1H NOESY spectra is described.