143850-71-9Relevant articles and documents
An efficient process for the synthesis of gem-dinitro compounds under high steric hindrance by nitrosation and oxidation of secondary nitroalkanes
Zhang, Jian,Hou, Tianjiao,Ling, Yifei,Zhang, Lin,Luo, Jun
supporting information, p. 2880 - 2883 (2018/06/25)
A new nitrosation and oxidation process to synthesize gem-dinitro compounds was accomplished by using nitryl chloride as nitrosation reagent and ozone as oxidizing agent. The main features of the present protocol include the compatibility to substances with high steric hindrance, high yields and mild reaction conditions. A plausible mechanism involving the formation of an intermediate of gem-nitrosonitro compound by means of single electron transfer was also proposed.
The Synthesis and Complete 1H and 13C NMR Spectral Assignment of 2,2,4,4,6,6-Hexanitroadamantane and its Precursor Nitroketones by 2D NMR Spectroscopy
Dave, Paritosh R.,Bracuti, Arthur,Axenrod, Theodore,Liang, Boming
, p. 5839 - 5846 (2007/10/02)
The synthesis of 2,2,4,4,6,6-hexanitroadamantane from the precursors 4,4,6,6-tetranitroadamantan-2-one and 4,4-dinitroadamantane-2,6-dione is reported.The complete 1H and 13C NMR assignment of these compounds by 2D 13C-1H shift correlated spectra. 1H-1H COSY spectra and 1H-1H NOESY spectra is described.