143859-77-2Relevant articles and documents
Push-pull type manganese(III)corroles: Synthesis, electronic structures and tunable interactions with ctDNA
Liang, Xu,Fang, Junjia,Li, Minzhi,Chen, Qiuyun,Mack, John,Molupe, Nthabeleng,Nyokong, Tebello,Zhu, Weihua
, p. 751 - 758 (2017)
The synthesis of three low symmetry A2B type Mn(III)triarylcorroles with meso-aryl substituents that provide push-pull electron-donating and -withdrawing properties is reported. An analysis of the structure-property relationships for the optical and redox properties has been carried out through a comparison with the results of theoretical calculations. The results demonstrate that A2B type Mn(III)triarylcorroles interact strongly with cell-free circulating tumor deoxyribonucleic acid (ctDNA) in solution, and that the interaction constants are enhanced when a stronger electron-donating substituent is introduced at the 10-position of the meso-triarylcorrole ligand.
Selective Synthesis of Tripyrranes, Tetrapyrranes, and Corroles
Aydin, Gokcen,Temelli, Baris,Unaleroglu, Canan
, p. 7583 - 7593 (2016/01/25)
A new, catalytic, and general methodology was developed for the direct synthesis of unsymmetrical AB-type tripyrranes by reaction of dipyrromethanesulfonamides with pyrrole. Key structure dipyrromethanesulfonamides were synthesized by the addition of meso
Efficient and versatile single pot approach to dipyrromethanes and bis(heterocyclyl)methanes
Singh, Kamaljit,Behal, Sonia,Hundal, Maninder Singh
, p. 6614 - 6622 (2007/10/03)
An efficient single pot route is presented involving the use of O, N-perhydro 1,3-heterocycles as carbonyl equivalents for the synthesis of 5-substituted dipyrromethanes, 5,10-disubstituted tripyrranes and bis(heterocyclyl)methanes.