Welcome to LookChem.com Sign In|Join Free

CAS

  • or

1438847-74-5

((phenyl2PC6H4)2BCl(η6-phenyl))RuCl is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1438847-74-5 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 1438847-74-5 Structure

  • Basic information

    1. Product Name: ((phenyl2PC6H4)2BCl(η6-phenyl))RuCl
    2. Synonyms:
    3. CAS NO:1438847-74-5
    4. Molecular Formula:
    5. Molecular Weight: 782.459
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1438847-74-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: ((phenyl2PC6H4)2BCl(η6-phenyl))RuCl(CAS DataBase Reference)
    10. NIST Chemistry Reference: ((phenyl2PC6H4)2BCl(η6-phenyl))RuCl(1438847-74-5)
    11. EPA Substance Registry System: ((phenyl2PC6H4)2BCl(η6-phenyl))RuCl(1438847-74-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1438847-74-5(Hazardous Substances Data)

1438847-74-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1438847-74-5 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,3,8,8,4 and 7 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1438847-74:
(9*1)+(8*4)+(7*3)+(6*8)+(5*8)+(4*4)+(3*7)+(2*7)+(1*4)=205
205 % 10 = 5
So 1438847-74-5 is a valid CAS Registry Number.

1438847-74-5Relevant articles and documents

A Ru-η6-arene complex as a C-based Lewis acid in the activation of hydrogen and hydrogenation catalysis

Boone, Michael P.,Stephan, Douglas W.

supporting information, p. 8508 - 8511 (2013/07/19)

The PBP ligand (Ph2PC6H4)2BPh was used to prepare ((Ph2PC6H4) 2B(Cl)(η6-Ph)RuCl (1) and subsequently [((Ph 2PC6H4)2B(η6-Ph)) RuCl][B(C6F5)4] (2). The latter species exhibited Lewis acidity on the η6-Ph ring, as reaction with Cy3P gave the donor-acceptor adduct [(Ph2PC 6H4)2B(η5-C6H 5-o-PCy3)RuCl][B(C6F5)4] (3). Steric frustration of this binding was seen with Mes3P, and yet the combination of 2 and Mes3P reacted with H2 to give a 2:1 mixture of 5-o and 5-p, two isomers of [(Ph2PC6H 4)2B(η5-C6H6)RuCl] (5), along with [Mes3PH][HB(C6F5)3]. Compound 2 behaves as C-based Lewis acid and thus can also be used for catalytic hydrogenation of aldimines at room temperature via a frustrated Lewis pair mechanism.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 1438847-74-5