1439241-70-9Relevant articles and documents
An alternately introduced heterometallo-supramolecular polymer: Synthesis and solid-state emission switching by electrochemical redox
Sato, Takashi,Higuchi, Masayoshi
, p. 5256 - 5258 (2013)
By utilizing different coordination properties of a lanthanide ion and a transition metal ion, a heterometallo-supramolecular polymer with Eu(iii) and Fe(ii) ions introduced alternately (polyEuFe) was precisely prepared via stepwise complexation of the metal ions to a new unsymmetrical ligand with both a dicarboxylate-substituted terpyridine and an unsubstituted terpyridine. The polymer showed unique, reversible on-off switching of the Eu(iii) luminescence by electrochemical redox of the Fe ions in the solid-state. The Royal Society of Chemistry 2013.