143948-95-2Relevant academic research and scientific papers
Synthetic approach to stemodin-A novel stereocontrolled construction of the stemodane system by the successive intramolecular Diels-Alder reactions
Toyota, Masahiro,Seishi, Takashi,Yokoyama, Masaharu,Fukumoto, Keiichiro,Kabuto, Chizuko
, p. 4581 - 4584 (2007/10/02)
The tetracyclic compound 18, possessing the stemodane skeleton, was synthesized from 1,4-cyclohexanedione monoethylene ketal 7. The key steps, 6→5 and 16→18, involve intramolecular Diels-Alder reaction.
