143955-87-7Relevant academic research and scientific papers
Kinetic hydricity of transition-metal hydrides toward trityl cation
Cheng,Bullock
, p. 4031 - 4033 (1995)
The kinetics of hydride transfer from a series of metal hydrides (MH) to Ph3C+BF4- (producing Ph3-CH and M - FBF3) have been studied by stopped-flow methods in CH2Cl3 solution. Second-order rate constants at 25°C span 5 orders of magnitude in kinetic hydricity, ranging from k = 5.0 × 101M-1 s-1 for HMn-(CO)5 to k = 4.6 × 105 M-1 s-1 for trans-HMo(CO)2-(PMe3)Cp.
