143969-34-0Relevant articles and documents
Hydroboration of Alkenes Catalysed by a Nickel N-Heterocyclic Carbene Complex: Reaction and Mechanistic Aspects
Chetcuti, Michael J.,Cornaton, Yann,Djukic, Jean-Pierre,Ritleng, Vincent,Ulm, Franck
, (2020/07/13)
The pentamethylcyclopentadienyl N-heterocyclic carbene nickel complex [Ni(η5-C5Me5)Cl(IMes)] (IMes=1,3-dimesitylimidazol-2-ylidene) efficiently catalyses the anti-Markovnikov hydroboration of alkenes with catecholborane in
Hydroboration of vinyl arenes using SiO2-supported rhodium catalysts
Geier, Michael J.,Geier, Stephen J.,Vogels, Christopher M.,Béland, Fran?ois,Westcott, Stephen A.
experimental part, p. 477 - 481 (2009/10/01)
The metal-catalyzed hydroboration of vinyl arenes using catecholborane (HBcat) and pinacolborane (HBpin) has been examined with SiO2- supported rhodium catalysts. Reactions with simple vinyl arenes (ArCH=CH 2) and HBcat using Rh(acac
Rh(I)-catalyzed asymmetric hydrosilylation and hydroboration/oxidation reactions using berens ligand
Marques, Carolina S.,Burke, Anthony J.
experimental part, p. 4207 - 4214 (2009/04/06)
The Berens ligand 2 was used in a number of Rh(I)-catalyzed asymmetric hydrosilylations of acetophenones under standard conditions, affording the corresponding 1-arylalcohols in ees up to 65%. Some novel Rh catalysts were generated in situ from the neutral precatalyst [Rh(μ-Cl)(COD)]2 and screened in the catalytic asymmetric hydroboration/oxidation of styrenes, gave enantioselectivities of up to 62%. Copyright Taylor & Francis Group, LLC.