143970-73-4

Upstream product

• 143970-68-7 cis-2-vinyl-3-benzylcyclopropanone 1,3-(2,2-dimethyl)propanediyl acetal 

Downstream Products

• 143970-77-8 cis-2-aza-1-phenyl-2-benzyl-3-methyl-cyclohexanone 
• 143970-77-8 trans-2-aza-1-phenyl-2-benzyl-3-methyl-cyclohexanone 
• 91897-73-3 (1E,4E)-1-phenyl-1,4-hexadien-3-one 
• 91897-74-4 (1E,4Z)-1-phenyl-1,4-hexadien-3-one 

Relevant academic research and scientific papers

Carbometalation of cyclopropenes. Stereoselective synthesis of divinyl ketones via 1,5-hydrogen migration reaction of vinylcyclopropanes

Stereoselective addition of a vinyl cuprate reagent to a cyclopropenone acetal (2) followed by in situ electrophilic trapping with an alkylating agent affords a cis-1-alkyl-2-vinylcyclopropanone acetal (3), which then undergoes thermal 1,5-hydrogen migrat

Carbometalation of Cyclopropenes. Stereoselective Synthesis of Divinyl Ketone Acetals by 1,5-Hydrogen Migration of Vinylcyclopropanes

Stereoselective vinylcupration of a cyclopropenone acetal (1), followed by in situ electrophilic trapping with an alkylating agent, affords via a cis-substituted vinylcyclopropane 2, which stereoselectively rearranges to the acetal of a cross-conjugate di