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1439937-07-1

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  • High Quality 99% 1439937-07-1 1,3-bis(5-bromo-4-(2-ethylhexyl)thiophen-2-yl)-5,7-bis(2-ethylhexyl)benzo[1,2-c;4,5-c']dithiophene-4,8-dione Manufacturer

    Cas No: 1439937-07-1

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  • 1,3-Bis(5-bromo-4-(2-ethylhexyl)thiophen-2-yl)-5,7-bis(2-ethylhexyl)benzo[1,2-c:4,5-c']dithiophene-4,8-dione

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1439937-07-1 Usage

Description

1,3-Bis(5-bromo-4-(2-ethylhexyl)thiophen-2-yl)-5,7-bis(2-ethylhexyl)benzo[1,2-c:4,5-c']dithiophene-4,8-dione, or?Benzodithiophene-2THBr-4EH, is a monomer for the synthesis of ow band-gap polymer semiconductors such as PBDD4T and PBDD4T-2F. It has applications in OPV (fullerene or fullerene-free), tandem organic solar cells, and OFETs.

Check Digit Verification of cas no

The CAS Registry Mumber 1439937-07-1 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,3,9,9,3 and 7 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1439937-07:
(9*1)+(8*4)+(7*3)+(6*9)+(5*9)+(4*3)+(3*7)+(2*0)+(1*7)=201
201 % 10 = 1
So 1439937-07-1 is a valid CAS Registry Number.

1439937-07-1Downstream Products

1439937-07-1Relevant articles and documents

A Fluorinated Polythiophene Derivative with Stabilized Backbone Conformation for Highly Efficient Fullerene and Non-Fullerene Polymer Solar Cells

Zhang, Shaoqing,Qin, Yunpeng,Uddin, Mohammad Afsar,Jang, Bomee,Zhao, Wenchao,Liu, Delong,Woo, Han Young,Hou, Jianhui

, p. 2993 - 3000 (2016/05/24)

Here, taking a polythiophene derivative (PBDD4T) as a starting polymer, we tried to increase the rotation barrier and hence stabilize its backbone conformation by introducing fluorine into the β- and β′-position of the α-linked bithiophene segments and then synthesized a new polymer named as PBDD4T-2F. Our results demonstrate that the rotation barrier between the α-linked bithiophene significantly increases after the fluorination, so PBDD4T-2F has a more stable backbone conformation than PBDD4T. Compared to PBDD4T, PBDD4T-2F shows stronger aggregation effect in solution state and more compact π-π stacking in solid thin film and also possesses deeper HOMO level. These properties make PBDD4T-2F being an ideal donor material in PSCs. When blended with PC71BM, a fullerene acceptor, the PBDD4T-2F-based device showed a power conversion efficiency (PCE) of 9.04%, which is 38% higher than that of the PBDD4T-based device; when blended with ITIC, a non-fullerene acceptor, the PBDD4T-2F-based device showed a PCE of 8.69%, which is almost 20 times higher than that of the PBDD4T-based device. What is more, the tandem cell, in which the blend of PBDD4T-2F:PC61BM was used for making the front subcell, exhibited a high PCE of 10.12%. The photovoltaic results indicate that the fluorination is an effective method to enhance interchain π-π interaction for the polythiophene and hence to tune its photovoltaic properties in PSCs, especially for the fullerene-free device based on ITIC.

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