144008-41-3

Upstream product

• 144070-44-0 (E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-1-phenyl-pent-3-en-2-ol 
• 144008-37-7 2,2,2-Trichloro-acetimidic acid (E)-(S)-1-benzyl-4-(tert-butyl-diphenyl-silanyloxy)-but-2-enyl ester 
• 144008-39-9 N-[(E)-(S)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-4-phenyl-but-2-enyl]-2,2,2-trichloro-acetamide 

Downstream Products

• 144008-43-5 (S)-2-Oxo-4-((E)-3-phenyl-propenyl)-oxazolidine-3-carboxylic acid tert-butyl ester 
• 144008-45-7 ((E)-(S)-1-Hydroxymethyl-4-phenyl-but-2-enyl)-carbamic acid tert-butyl ester 
• 144008-47-9 (E)-(S)-2-tert-Butoxycarbonylamino-5-phenyl-pent-3-enoic acid 

Relevant academic research and scientific papers

Synthesis of (E)-β,γ-unsaturated α-aminoacids by rearrangement of allyltrichloracetimidates

Pure (E)-β,γ-unsaturated α-aminoacids of high enantiomerical purity were synthesized by Pd(II) catalyzed rearrangement of trichloracetimidates derived from optically pure monoprotected diallylalcohols. After cyclisation of the resulting N-trichloracetyl a