144019-43-2Relevant academic research and scientific papers
Synthesis of N-Boc-Protected 1-Amino-3-alken-2-ols from Allylic Carbamates via Palladium(II)-Catalyzed Oxidative Cyclization
Benthem, Rolf A. T. M. van,Hiemstra, Henk,Speckamp, W. Nico
, p. 6083 - 6085 (2007/10/02)
Methyl glyoxylate adducts of N-Boc-protected allylic amines cyclize in the presence of catalytic Pd(OAc)2 and excess Cu(OAc)2 in DMSO to 5-(1-alkenyl)-2-(methyoxycarbonyl)oxazolidines.These heterocycles are readily converted to unsaturated.N-Boc-protected
