14402-00-7Relevant articles and documents
Di- and tri-1-(1-naphthyl)ethylamino-substituted 1,3,5-triazine derivatives: A new class of versatile chiral auxiliaries for NMR spectroscopy
Uccello-Barretta, Gloria,Iuliano, Anna,Franchi, Emanuela,Balzano, Federica,Salvadori, Piero
, p. 9197 - 9203 (1998)
2-Chloro-4,6-bis[(R)-1-(1-naphthyl)ethylamino]-1,3,5-triazine, 2,4,6- tris[(R)-1-(1-naphthyl)ethylamino]-1,3,5-triazine, and 2,4-bis[(R)-1-(1- naphthyl)ethylamine]-6-[(S)-1-(1-naphthyl)ethylamino]-1,3,5-triazine have been synthesized, and their efficiency and versatility as chiral solvating agents for the determination by NMR of the enantiomeric composition of derivatized or underivatized chiral compounds have been demonstrated.
Chiral mono- And dicarbamates derived from ethyl (: S)-lactate: convenient chiral solvating agents for the direct and efficient enantiodiscrimination of amino acid derivatives by 1H NMR spectroscopy
Balzano, Federica,Uccello-Barretta, Gloria
, p. 4869 - 4875 (2020/02/19)
New chiral solvating agents (CSAs) for NMR spectroscopy have been obtained from ethyl (S)-lactate, a very cheap commercially available product. By a sequence of simple chemical modifications of its functional groups, monocarbamoylated and dicarbamoylated