144030-52-4Relevant academic research and scientific papers
Diphenylacetylene Complexes of Tungsten containing ?-Acceptor Ligands
Clark, George R.,Nielson, Alastair J.,Rae, A. David,Rickard, Clifton E. F.
, p. 1783 - 1790 (2007/10/02)
Reaction of PhC2Ph with gave 1 for which IR and NMR spectral data indicated cis-chloro ligands, trans phosphines and mutually-cis diphenylacetylene ligands.This geometry was confirmed by X-ray crystallography.T
The Synthesis of Octahedral Mixed Bis-alkyne and Alkyne-alkene Complexes of Tungsten
Clark, George R.,Nielson, Alastair J.,Rae, A. David,Rickard, Clifton E. F.
, p. 1069 - 1070 (2007/10/02)
Replacement of a phosphine ligand in by PhCCPh, PhCCH and HCCH, or reduction of in the presence of MeC2Me and Me(CH2)2C2Me yields mixed bis-alkyne complexes; under ethylene or propene the reduction reactions afford mixed alkyne-alkene complexes, and the structure of has been confirmed by X-ray crystallography.
