144050-25-9Relevant academic research and scientific papers
Accurate determination of the extent to which an S(E)2' reaction of an allylsilane is anti
Buckle,Fleming,Gil
, p. 4479 - 4482 (1992)
The E and Z allylsilanes E-1 and Z-1 have been prepared essentially 100% geometrically and enantiomerically pure; their S(E)2' reactions with adamantyl chloride are highly, but not completely, stereospecific.
Accurate determination of the extent to which the SE2′ reactions of an allenylsilane are stereospecifically anti
Buckle, Michael J. C.,Fleming, Ian
, p. 2383 - 2386 (2007/10/02)
The allenylsilane 1 has been prepared in high enantiomeric purity (98% e.e.); its SE2′ reaction with adamantyl chloride and isobutyraldehyde are stereospecifically anti to a very high degree (>99:1).
