1440530-23-3Relevant articles and documents
A synthetic route to a molecular galloxane dihydroxide and its group 4 heterobimetallic compounds
Bernabe-Pablo, Erandi,Jancik, Vojtech,Moya-Cabrera, Monica
, p. 6944 - 6950 (2013)
Controlled hydrolysis of MeLGaCl2 (MeL = HC[(CMe)N(2,4,6-Me3C6H2)]2 -) (1) in the presence of a N-heterocyclic carbene, as a HCl acceptor, led to the unprecedented molecular galloxane dihydroxide [{ MeLGa(OH)}2(μ-O)] (2) in high yield. Compound 2 was used in the assembly of the heterobimetallic galloxanes with group 4 metals [{(MeLGa)2(μ-O)}(μ-O)2{M(NR 2)2}] (M = Ti, R = Me (6); M = Zr (7), Hf (8), R = Et).