1440537-82-5Relevant articles and documents
Regio- and stereoselective direct N-alkenylation of indoles via Pd-catalyzed aerobic oxidation
Wu, Ge,Su, Weiping
, p. 5278 - 5281 (2013)
With two different sets of Pd catalyst systems in hand, indoles, whether bearing a C3-substituent or not, can be directly alkenylated on their nitrogen atoms using a sterically and electronically diverse array of alkenes, in which the high regio- and stereoselectivity are dependent on the nature of the alkenes used. This process proceeds in generally good yields and is compatible with a broad range of functional groups.
Palladium-catalyzed oxidative cross-coupling of N-tosylhydrazones with indoles: Synthesis of N-vinylindoles
Zeng, Xiaobao,Cheng, Guolin,Shen, Jinhai,Cui, Xiuling
, p. 3022 - 3025 (2013/07/26)
A general and efficient palladium-catalyzed oxidative cross-coupling reaction of N-tosylhydrazones with indoles providing N-vinylindoles has been developed. The reaction proceeds smoothly with various indoles and N-tosylhydrazones in a stereocontrolled ma