1440544-57-9Relevant academic research and scientific papers
Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation: Formal synthesis of aspergillide A
Zeng, Jing,Ma, Jimei,Xiang, Shaohua,Cai, Shuting,Liu, Xue-Wei
, p. 5134 - 5137 (2013)
Mild and sweet: The title reaction proceeds under mild conditions with high regio- and diastereoselectivity (see scheme, PG=protecting group, DiPPF=1,1′-bis(diisopropylphosphino)ferrocene). This reaction is suitable for a wide range of glycal-derived γ-ketone esters and affords C-glycosides with exclusive β-selectivity. The method was further applied to a concise formal synthesis of aspergillideA. Copyright
