144079-85-6Relevant academic research and scientific papers
A facile Claisen rearrangement involving the transient tautomeric enamine forms of α-allyloxy and α-propargyloxyimines
Desmaele,Champion
, p. 4447 - 4450 (1992)
α-Allyloxyimines rearrange smoothly to 2-amino-2-allyl-ketones by heating at 80°C for few hours, by Claisen rearrangement of the tautomeric secondary enamine. Similarly α-propargyloxyimine gave 2-amino-2-allenyl-ketones. By contrast, 2-benzyloxyimines aff
