1440943-36-1

Basic information

• Product Name: (1S,2R,4S,5R)-2-(hydroxymethyl)-4-phenylbicyclo[3.2.1]oct-6-en-3-one
• CAS NO: 1440943-36-1
• Molecular Weight: 228.291
• Mol File: 1440943-36-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2R,4S,5R)-2-(hydroxymethyl)-4-phenylbicyclo[3.2.1]oct-6-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,4S,5R)-2-(hydroxymethyl)-4-phenylbicyclo[3.2.1]oct-6-en-3-one(1440943-36-1)
• EPA Substance Registry System: (1S,2R,4S,5R)-2-(hydroxymethyl)-4-phenylbicyclo[3.2.1]oct-6-en-3-one(1440943-36-1)

Safety Data

• Hazardous Substances Data: 1440943-36-1(Hazardous Substances Data)

Upstream product

• 1440943-93-0 (S,Z)-triethyl((1-(oxiran-2-yl)-2-phenylvinyl)oxy)silane 
• 542-92-7 cyclopenta-1,3-diene 
• 160732-08-1 (S)-1-(oxiran-2-yl)-2-phenylethanone 
• 766-04-1 benzyllithium 

Relevant articles and documents

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A f(oxy) allyl: The intermolecular (4+3) cycloaddition of enantiomerically enriched epoxy enolsilanes produces cycloadducts with up to 99 % ee, thus implying the reaction does not proceed by the putative achiral oxyallyl cation intermediate, but through a transiently chiral electrophile which retains the stereochemical information of the epoxide (see scheme; TES=triethylsilyl, Tf=trifluoromethanesulfonyl). Copyright