1441-22-1

Upstream product

• 892-20-6 triphenylstannane 
• 108-98-5 thiophenol 
• 931-59-9 benzenesulfenyl chloride 
• 882-33-7 diphenyldisulfane 
• 1954-39-8 triphenylstannyl isocyanate 
• 1954-34-3 triphenyltin isothiocyanate 
• 894-09-7 iodotriphenylstannane 
• 962-89-0 triphenyltin bromide 
• 639-58-7 triphenyltin chloride 
• 1064-10-4 hexaphenylditin 
• 4167-90-2 lithium triphenylstannide 
• 57139-22-7 potassium p-methoxylbenzohydroxamate 
• 76-63-1 allytriphenyltin 

Downstream Products

• 1064-10-4 hexaphenylditin 
• 962-89-0 triphenyltin bromide 
• 17019-36-2 (benzenethiolato)methylmercury(II) 
• 894-09-7 iodotriphenylstannane 
• 639-58-7 triphenyltin chloride 
• 1954-34-3 triphenyltin isothiocyanate 
• 1954-39-8 triphenylstannyl isocyanate 
• 1158-51-6 triphenyltin azide 
• 91258-84-3 (C₆H₅)3SnCCC₆H₄F 
• 86774-18-7 W(CO)5((C₆H₅)3SnS(C₆H₅)) 
• 882-33-7 diphenyldisulfane 

Relevant academic research and scientific papers

Novel room light-induced disproportionation reaction of organo-ditin and -dilead compounds with organic dichalcogenides: An efficient salt-free route to organo-tin and -lead chalcogenides

Disproportionation of organo-ditin and -dilead compounds (R3M)2 (M = Sn, Pb) with organic dichalcogenides (R'Z)2 (Z = S, Se, Te) is efficiently promoted by room light to produce the corresponding organo-tin and -lead chalc

Reactivity of some di- and triphenyltin(m) hydroxamates with ligands containing labile protons

The reactivity of di- and triphenyltin(IV) hydroxamate complexes of composition (C6H5)2SnCl2-n(XBHA)n and (C6H5)3Sn(XBHA) (n = 1 and 2; X = p-OMe, o-Cl, p-NO2; BHA = anion of XArCONHOK) with ligands containing labile protons such as acetylacetone (acacH), dibenzoylmethane (dbmH), salicylaldehyde (salH) and o-chlorophenol and thiophenol has been studied to investigate the preferential attack on Sn-C, Sn-Cl or Sn-O bond. The title complexes do not react with the chelating ligands. However, the reactions of (C6H5)2SnCl(XBHA) with sodium salt of the chelating ligands NaL (L= acac, dbm and sal) readily proceed to yield the mixed ligand complexes of composition (C6H5)2Sn(XBHA)*L, while the treatment of (C6H5)2Sn(XBHA)2 and (C6H5)3Sn(XBHA) with phenols results in the complete displacement of the hydroxamate group with the phenolate ion.

HALOGEN AND PEUDOHALOGEN SUBSTITUTION OF SOME ADAMANTANOID CHALCOGENATE CLUSTERS (2-) USING METHYLMERCURY AND TRIPHENYLTIN DERIVATIVES. A MULTINUCLEAR NUCLEAR MAGNETIC RESONANCE STUDY

Multinuclear nmr (1H, 77Se, 111/113Cd, 119Sn, 199Hg, as appropriate) has been used to study Y(1-) - EPh(1-) exchange in Me2CO or MeCN between (RnM'Y (RnM' = Ph3Sn or MeHg; Y = Cl, Br, I, NCO, or NCS) and the adamantane-like anions (2-) (E = S, M = Zn, Cd, or Co; E = Se, M = Zn or Cd), as their tetraalkylammonium salts.Quantitative terminal substitution of the clusters occurs in most cases, giving 4-x(MY)x>(2-) (x = 1-4).However, reaction is incomplete for M = Cd, E = S or Se, RnM'Y = Ph3SnNCO or Ph3SnNCS and for M = Zn or Co, E = S, RnM'Y = MeHgI.Differences in the extents of reaction for Ph3SnY and MeHgY are consistent with the position of equilibrium in MeHgY:Ph3SnEPh mixtures.Group interchange provides a convenient alternative synthesis of the known halogen-substituted clusters (2-) (M = Zn or Cd, Y = Cl, Br, or I; M = Co, Y = Cl), and the first syntheses of (2-) (Y = Br or I) and various pseudohalogen-substituted adamantanoid anions.The nuclei used for full direct nmr characterization of the new clusters in solution were: 77Se and 113Cd for 4-x(CdY)x>(2-) (x = 1-4; Y = NCO or NCS); 77Se for 4-x(ZnY)x>(2-) (x = 1-4, Y = NCO or NCS); 113Cd for 4-x(CdY)x>(2-) (x = 1-4; Y = NCO or NCS); 1H for (2-) (Y = Br, I, NCO, or NCS).The first solution 1H nmr spectrum of (2-) is also reported.

Thioether complexes of tungsten hexacarbonyl

The preparation of a series of organic and organometallic thioethers R3MSR' (M = C,Si,Ge, or Sn) is reported.From these, several new compounds of type 1 are synthesized, some of which contain para-substituted aryl functions for R and R'.In hexane solution in the carbonyl streching region of the ir the uv there is evidence for a degree of multiple bonding, at least in the M - S - WW - CO portion of these molecules.Multiple bonding extending into aromatic R or R'is small or non-existent and cannot be assessed precisely because of spontaneous decomposition of the complexes.All the complexes undergo a thermally initiated decomposition, the case of which depends on the nature of R, R', and M.The unusual W(I) thiolate cis-2 is the termal decomposition product.

Functionally substituted organotin compounds I. Addition of thiols to alkenyltin compounds

3-(Trialkylstannyl)propyl aryl sulphides (R3SnCH2CH2CH2SR′; R = Me, Et, Bu; R′ = Ph, p-tolyl) were prepared by the addition of arenethiols to allyltrialkyltin compounds. Preferential cleavage of the allyl group