1441002-36-3

Basic information

• Product Name: (Z)-3-(bis(3,5-dimethoxyphenyl)phosphoryl)-3-(1-hydroxycyclopropyl)-1,2-diphenylprop-2-en-1-one
• Synonyms: (Z)-3-(bis(3,5-dimethoxyphenyl)phosphoryl)-3-(1-hydroxycyclopropyl)-1,2-diphenylprop-2-en-1-one
• CAS NO: 1441002-36-3
• Molecular Weight: 584.606
• Mol File: 1441002-36-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-3-(bis(3,5-dimethoxyphenyl)phosphoryl)-3-(1-hydroxycyclopropyl)-1,2-diphenylprop-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3-(bis(3,5-dimethoxyphenyl)phosphoryl)-3-(1-hydroxycyclopropyl)-1,2-diphenylprop-2-en-1-one(1441002-36-3)
• EPA Substance Registry System: (Z)-3-(bis(3,5-dimethoxyphenyl)phosphoryl)-3-(1-hydroxycyclopropyl)-1,2-diphenylprop-2-en-1-one(1441002-36-3)

Safety Data

• Hazardous Substances Data: 1441002-36-3(Hazardous Substances Data)

Upstream product

• 1376626-55-9 3-cyclopropylidene-1,2-diphenyl-3-prop-2-en-1-one 
• 95704-30-6 tris(3,5-dimethoxyphenyl)phosphane 

Relevant articles and documents

Hydroxyphosphinylation reaction of 3-cyclopropylideneprop-2-en-1-ones via C-P σ-bond cleavage

An unexpected hydroxyphosphinylation of 3-cyclopropylideneprop-2-en-1-ones with phosphines has been observed. This method provides a unique regio- and stereoselective synthesis of highly functionalized 1-dialkylphinyl-3-oxo-(1Z)- alkenyl cyclopropanols with important potentials. The reaction displays an unusual mechanistic feature - a highly selective cleavage of C-P σ bonds in phosphines.