144118-52-5

Basic information

• Product Name: (1S,2S,4S,6S)-2-methoxy-6-benzylhydroxy-1-ethoxycarbonylmethylene-3-oxabicyclo<2.2.1>heptane
• CAS NO: 144118-52-5
• Molecular Weight: 320.386
• Mol File: 144118-52-5.mol

Chemical Properties

• CAS DataBase Reference: (1S,2S,4S,6S)-2-methoxy-6-benzylhydroxy-1-ethoxycarbonylmethylene-3-oxabicyclo<2.2.1>heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,4S,6S)-2-methoxy-6-benzylhydroxy-1-ethoxycarbonylmethylene-3-oxabicyclo<2.2.1>heptane(144118-52-5)
• EPA Substance Registry System: (1S,2S,4S,6S)-2-methoxy-6-benzylhydroxy-1-ethoxycarbonylmethylene-3-oxabicyclo<2.2.1>heptane(144118-52-5)

Safety Data

• Hazardous Substances Data: 144118-52-5(Hazardous Substances Data)

Upstream product

• 144118-95-6 methyl-3-O-benzyl-4-desoxy-2-O-p-methoxybenzyl-6-O-trityl-α-D-xylo-hexopyranoside 
• 144118-94-5 methyl-3-O-benzyl-4-desoxy-6-O-trityl-α-D-xylo-hexopyranoside 
• 144118-97-8 methyl-3-O-benzyl-6-bromo-5,6-didesoxy-2-O-p-methoxybenzyl-α-D-xylo-hexopyranoside 
• 144118-96-7 methyl-3-O-benzyl-4-desoxy-2-O-p-methoxybenzyl-α-D-xylo-hexopyranoside 
• 144118-51-4 methyl-3-O-benzyl-6-bromo-4,6-didesoxy-2-carbethoxymethylidene-α-D-threohexopyranoside 

Downstream Products

• 144118-53-6 (1S,2S,3S,5S)-5-benzyloxy-3-methoxy-4-methoxycarbonylmethyl-2-oxabicyclo<2.2.1>heptane 

Relevant articles and documents

FREE RADICAL REACTIONS OF CARBOHYDRATE DERIVATIVES IN THE SYNTHESIS OF CARBOCYCLIC COMPOUNDS. 1. INTRAMOLECULAR C2-C6 CYCLIZATION OF MONOSACCHARIDES - A NEW ROUTE TO SUBSTITUTED CYCLOPENTANES

The feasibility of adopting a new approach to the preparation of chiral carbocyclic compounds has been demonstrated by experimental.Synthesis was achieved by way of intramolecular free radical C2-C6 cyclization of carbohydrate deriva