144141-07-1

Basic information

• Product Name: (2S,3S)-2-Methoxymethoxy-3-phenyl-butyraldehyde
• CAS NO: 144141-07-1
• Molecular Weight: 208.257
• Mol File: 144141-07-1.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S)-2-Methoxymethoxy-3-phenyl-butyraldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-2-Methoxymethoxy-3-phenyl-butyraldehyde(144141-07-1)
• EPA Substance Registry System: (2S,3S)-2-Methoxymethoxy-3-phenyl-butyraldehyde(144141-07-1)

Safety Data

• Hazardous Substances Data: 144141-07-1(Hazardous Substances Data)

Upstream product

• 34713-70-7 2-Phenylpropanal 

Downstream Products

• 144141-05-9 (2S,3S,4S)-6-Methyl-2-phenyl-heptane-3,4-diol 
• 144141-06-0 (4R,5R)-4-Isobutyl-2,2-dimethyl-5-((S)-1-phenyl-ethyl)-[1,3]dioxolane 
• 144141-05-9 (2S,3R,4R)-6-Methyl-2-phenyl-heptane-3,4-diol 

Relevant articles and documents

Very High Diastereofacial Stereoselectivity in the α-Methoxy Organolead-Aldehyde Condensation. Stereocontrol of Three Contiguous Chiral Centres

The reaction of the α-methoxylead derivative 1a with 2-phenylpropanal in the presence of TiCl4 gave the 1,2-syn-2,3-syn product 2 with very high diastereoselectivity: 1,2-syn/1,2-anti = 95/5 and 2,3-syn/2,3-anti = 100/0.