144150-76-5

Basic information

• Product Name: 4-phenoxyphenyl 4-methylbenzenesulfonate
• Synonyms: 4-phenoxyphenyl 4-methylbenzenesulfonate
• CAS NO: 144150-76-5
• Molecular Weight: 340.4
• Mol File: 144150-76-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-phenoxyphenyl 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-phenoxyphenyl 4-methylbenzenesulfonate(144150-76-5)
• EPA Substance Registry System: 4-phenoxyphenyl 4-methylbenzenesulfonate(144150-76-5)

Safety Data

• Hazardous Substances Data: 144150-76-5(Hazardous Substances Data)

Upstream product

• 101-84-8 diphenylether 
• 104-15-4 toluene-4-sulfonic acid 
• 831-82-3 4-Phenoxyphenol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 2974-06-3 1-phenoxy-4-(phenylsulfanyl)benzene 
• 1655-69-2 1-methoxy-4-phenoxy-benzene 
• 27798-36-3 1-benzyl-4-phenoxybenzene 
• 139-59-3 4-phenoxyanilin 
• 445283-13-6 4-phenoxy-2-(4-toluenesulfonyl)phenoxyethyl 4-toluenesulfonate 
• 445283-11-4 2-{2-[4-phenoxy-2-(toluene-4-sulfonyl)-phenoxy]-ethoxy}-tetrahydro-pyran 
• 445283-12-5 4-phenoxy-2-(4-toluenesulfonyl)phenoxyethanol 
• 445283-10-3 4-phenoxy-2-(4-toluenesulfonyl)phenol 
• 101-84-8 diphenylether 

Relevant articles and documents

Copper-Catalyzed Regioselective C-H Sulfonyloxylation of Electron-Rich Arenes with p-Toluenesulfonic Acid and Sulfonyloxylation of Aryl(mesityl)iodonium Sulfonates

Copper-catalyzed regioselective C-H sulfonyloxylation of electron-rich arenes with p-toluenesulfonic acid has been developed. Electron-rich benzene derivatives and heteroarenes can undergo this C-H sulfonyloxylation reaction to generate aryl tosylates. Furthermore, sulfonyloxylation of aryl(mesityl)iodonium sulfonates has also been investigated. Both aryl(mesityl)iodonium tosylates and triflates can react smoothly to get aryl sulfonates. The formed aryl sulfonates can be converted to phenols, as well as used as good partners of cross-coupling reactions.

Facile Deoxygenation of Phenols and Enols Using Sodium Borohydride-Nickel Chloride

A facile deoxygenation reaction of phenol and 1,3-dicarbonyl compounds was investigated.Phenols, enolizable 1,3-diketones and 3-ketoesters were converted into the toluene-p-sulfonates which were reduced by a sodium borohydride-nickel chloride system to give the deoxygenated aromatic compounds, alcohols and esters, respectively.