144192-98-3Relevant academic research and scientific papers
Cobalt-Mediated Synthesis of Angular [4]Phenylene: Structural Characterization of a Metallacyclopentadiene(Alkyne) Intermediate and Its Thermal and Photochemical Conversion
Dosa, Peter I.,Whitener, Glenn D.,Vollhardt, K. Peter C.,Bond, Andrew D.,Teat, Simon J.
, p. 2075 - 2078 (2007/10/03)
(Matrix Presented) The first X-ray crystal structure of a mononuclear metallacyclopentadiene(alkyne) complex has been obtained. This type of metallacycle is believed to be the key intermediate in the cobalt-mediated [2 + 2 + 2]cycloaddition of alkynes. Th
Synthetic Studies Related to the Esperamicin/Calicheamicin Aglycone: Efficient Construction of a Homochiral Oxabicyclo Analogue from D-Xylose
Dancy, Isabelle,Skrydstrup, Troels,Crevisy, Christophe,Beau, Jean-Marie
, p. 799 - 800 (2007/10/02)
The synthesis of a bicyclic model of the calicheamicin/esperamicin aglycone is described using a highly efficient and stereospecific Nozaki-Kishi reaction for the ring closure.
