144193-95-3Relevant academic research and scientific papers
Desulfonylative Methenylation of β-Keto Sulfones
Pandey, Ganesh,Vaitla, Janakiram
supporting information, p. 4890 - 4893 (2015/10/12)
A one-step strategy for the synthesis of α-methenyl ketones from β-keto sufones is reported. Success of the methodology is elaborated for the synthesis of chromanones and isoflavanones in one-step.
Stereocontrolled synthesis of 1,3-diols from enones: Cooperative lewis base-mediated intramolecular carbonyl hydrosilylations
Medina, Casey,Carter, Kyle P.,Miller, Michael,Clark, Timothy B.,O'Neil, Gregory W.
supporting information, p. 9093 - 9101 (2013/10/08)
A streamlined synthesis of β-hydroxy ketone substrates has been developed to further investigate a recently discovered cooperative Lewis base-mediated intramolecular carbonyl hydrosilylation reaction. The synthesis features an enone β-borylation/oxidation
Total synthesis of (+)-phomopsolide C by ring-size selective ring-closing metathesis/cross-metathesis
Michaelis, Simon,Blechert, Siegfried
, p. 5513 - 5516 (2007/10/03)
(Chemical Equation Presented) A new strategy for the synthesis of chiral 6-substituted 5,6-dihydro-5-hydroxypyran-2-ones by ring-size selective ring-closing metathesis (RCM) and its application to a short total synthesis of (+)-phomopsolide C are describe
Stereoselection in Thermal Asymmetric Diels-Alder Reactions. Electronic vs Steric Effects
Stammen, Blanda,Berlage, Ulrich,Kindermann, Richard,Kaiser, Manfred,Guenther, Barbara,et al.
, p. 6566 - 6575 (2007/10/02)
Experimental evidence was found for an electronic contribution favoring the cisoid conformation of α,β-unsaturated carbonyl compounds in thermal Diels-Alder transition states.
