144204-42-2

Basic information

• Product Name: bis(2,6-dimethylbenzenethiolate)(η6-p-cymene)ruthenium
• Synonyms: bis(2,6-dimethylbenzenethiolate)(η6-p-cymene)ruthenium
• CAS NO: 144204-42-2
• Molecular Weight: 509.742
• Mol File: 144204-42-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(2,6-dimethylbenzenethiolate)(η6-p-cymene)ruthenium(CAS DataBase Reference)
• NIST Chemistry Reference: bis(2,6-dimethylbenzenethiolate)(η6-p-cymene)ruthenium(144204-42-2)
• EPA Substance Registry System: bis(2,6-dimethylbenzenethiolate)(η6-p-cymene)ruthenium(144204-42-2)

Safety Data

• Hazardous Substances Data: 144204-42-2(Hazardous Substances Data)

Upstream product

• 118-72-9 2,6-dimethylbenzene-1-thiol 
• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 34878-61-0 sodium 2,6-dimethylphenylthiolate 

Downstream Products

• 187409-45-6 [(CO)2(SC6H3Me2-2,6)Ru(μ-SC6H3Me-2,6)3Ru(CO)3] 
• 187409-23-0 trans-[Ru(SC₆H₃Me₂-2,6)2(CNtBu)4] 

Relevant articles and documents

16-Electron Half-sandwich Ru(II)-Thiolate Complexes, Ru(SAr)2(η6-p-cymene) (Ar = 2,6-dimethylphenyl and 2,4,6-triisopropylphenyl)

Treatment of 2 with sodium 2,6-dimethylbenzenethiolate or sodium 2,4,6-triisopropylbenzenethiolate in methanol afforded a mononuclear five-coordinated ruthenium thiolate complex, Ru(SAr)2(p-cymene) (2a: Ar = 2,6-dimethylphenyl; 2b: 2,4,6-triisopropylphenyl), whose structure is determined by X-ray analysis of 2a.