144260-75-3Relevant academic research and scientific papers
New Synthesis of α-Amino Acid N-Carboxy Anhydrides through Baeyer-Villiger Oxidation of α-Keto β-Lactams
Palomo, Claudio,Aizpurua, Jesus M.,Ganboa, Inaki,Carreaux, Francois,Cuevas, Carmen,et al.
, p. 3123 - 3130 (2007/10/02)
A conceptually new route for the generation of optically active α-aminoacid N-carboxy anhydrides (NCAs) and hence α-amino acid derivatives is described.The strategy developed is simple and consists of the oxidation of α-hydroxy β-lactams to the correspond
Stereocontrolled Synthesis of 3,5-Dialkyl-4-Amino Pyrrolidin-2-ones From β-Lactams as Chiral Templates.
Palomo, Claudio,Cossio, Fernando P.,Cuevas, Carmen,Odriozola, Jose M.,Ontoria, Jesus M.
, p. 4827 - 4830 (2007/10/02)
A new approach to 3,5-dialkyl pyrrolidin-2-ones by intramolecular rearrangement of both cis and trans 3-alkyl-4-(1-aminoalkyl) β-lactams is described.
