1442635-87-1

Basic information

• Product Name: (S)-1-(2-(4-isopropoxy-3,5-dimethoxybenzyl)-1,3-dithian-2-yl)pentan-2-ol
• Synonyms: (S)-1-(2-(4-isopropoxy-3,5-dimethoxybenzyl)-1,3-dithian-2-yl)pentan-2-ol
• CAS NO: 1442635-87-1
• Molecular Weight: 414.631
• Mol File: 1442635-87-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-(2-(4-isopropoxy-3,5-dimethoxybenzyl)-1,3-dithian-2-yl)pentan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-(2-(4-isopropoxy-3,5-dimethoxybenzyl)-1,3-dithian-2-yl)pentan-2-ol(1442635-87-1)
• EPA Substance Registry System: (S)-1-(2-(4-isopropoxy-3,5-dimethoxybenzyl)-1,3-dithian-2-yl)pentan-2-ol(1442635-87-1)

Safety Data

• Hazardous Substances Data: 1442635-87-1(Hazardous Substances Data)

Upstream product

• 1442635-86-0 2-(4-isopropoxy-3,5-dimethoxybenzyl)-1,3-dithiane 
• 123731-68-0 (S)-1,2-epoxypentane 

Downstream Products

• 1442635-88-2 (S)-4-hydroxy-1-(4-isopropoxy-3,5-dimethoxyphenyl)heptan-2-one 
• 1442635-89-3 (2S,4S)-2-hydroxy-1-(4-isopropoxy-3,5-dimethoxyphenyl)heptan-4-yl propionate 
• 28890-33-7 monocerin 
• 30270-61-2 (2S,3aR,9bR)-2,3,3a,9b-tetrahydro-6,7,8-trimethoxy-2-propyl-5H-furol(3,2-c)⁽²⁾benzopyran-5-one 

Relevant articles and documents

Asymmetric total synthesis of fusarentin 6-methyl ether and its biomimetic transformation into fusarentin 6,7-dimethyl ether, 7-O-demethylmonocerin, and (+)-monocerin

A concise asymmetric total synthesis of a fusarentin ether (1) with sequential biomimetic transformation to its analogues fusarentin 6,7-dimethyl ether (2), 7-O-demethylmonocerin (3), and (+)-monocerin (4) has been accomplished. The cis-fused furobenzopyranones of 7-O-demethylmonocerin (3) and (+)-monocerin (4) were efficiently constructed via an intramolecular nucleophilic trapping of a quinonemethide intermediate, which was obtained by benzylic oxidation of fusarentin 6-methyl ether (1) using hypervalent iodine reagent.