144293-60-7Relevant academic research and scientific papers
Metal-free, aerobic dioxygenation of alkenes using hydroxamic acids
Schmidt, Valerie A.,Alexanian, Erik J.
supporting information; scheme or table, p. 4491 - 4494 (2010/08/21)
(Chemical equation presented) One dioxygenation please, hold the metal: In the presence of either oxygen or air as the sole oxidant and external oxygen atom source, a variety of unsaturated hydroxamic acids afford cyclic hydroxamates that are readily converted into 1,2-diols, with the potential for high levels of reaction stereocontrol.
Direct substitution of secondary allylic alcohols with O-silylated ketene acetals in 3.0 M lithium perchlorate-diethyl ether - An alternative to the [1,3] sigmatropic rearrangement of allyl vinyl ethers
Grieco,Collins,Henry Jr.
, p. 4735 - 4738 (2007/10/02)
Allylic alcohols of type 1 undergo unprecedented substitution with O-silylated ketene acetals in 3.0 M lithium perchlorate-diethyl ether.
