144297-35-8Relevant academic research and scientific papers
Rare-Earth-Catalyzed C?H Silylation of Aromatic Heterocycles with Hydrosilanes
Xu, Wenxuan,Teng, Huailong,Luo, Yong,Lou, Shaojie,Nishiura, Masayoshi,Hou, Zhaomin
supporting information, p. 753 - 756 (2020/02/25)
The catalytic C?H silylation of a variety of aromatic heterocycles such as furan, pyrrole and thiophene derivatives with secondary hydrosilanes has been achieved by using an yttrium metallocene complex. This protocol provides an efficient and straightforward way for the synthesis of a series of silylated heteroaromatic compounds containing tertiary silane moieties without the need for an additive or H2 acceptor.
Failure in Several Attempts to Prepare Arylsilyl-lithium Reagents by the Gilman Cleavage of Disilanes with Lithium
Rahman, Noorsaadah Abd.,Fleming, Ian,Zwicky, Anna B.
, p. 2401 - 2408 (2007/10/02)
Several diarylsilanes 5,9 and 11 do not cleave with lithium in THF to give silyl-lithium reagents, in contrast to diphenyltetramethyldisilane 2, which is well known to give phenyldimethylsilyl-lithium.Trityldiphenylsilyl bromide 13 reacts with lithium to
