1443384-39-1Relevant articles and documents
Pressure effects in the synthesis of isomeric rotaxanes
Sorensen, Anne,Andersen, Sissel S.,Flood, Amar H.,Jeppesen, Jan O.
supporting information, p. 5936 - 5938 (2013/07/11)
Pressure not only influences the yield in the synthesis of a two-station [2]rotaxane, it also determines the distribution of the co-conformational isomers. At high pressure cyclobis(paraquat-p-phenylene) is preferentially assembled around a monopyrrolotetrathiafulvalene unit, while at low pressure it is preferentially assembled around a hydroquinone unit.