144348-02-7

Upstream product

• 54795-27-6 5-methyl-3,4-hexadien-1-ol 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 265983-48-0 3-acetoxy-1-(tert-butyldiphenylsilyloxy)-4-hexyne 
• 265983-47-9 3-(tert-butyldiphenylsilyloxy)-4-hexyn-3-ol 
• 265983-49-1 1-(tert-butyldiphenylsilyloxy)-5-methyl-3,4-hexadiene 
• 30333-01-8 5-methylhexa-3,4-dienoic acid ethyl ester 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1025712-90-6 1-(benzyloxy)-2-(5-methyl-3,4-hexadienyl)benzene 
• 147375-90-4 4-methyl-N-(6-methylhepta-4,5-dien-1-yl)benzenesulfonamide 
• 906542-90-3 methyl 7-methyl-2,2-diphenylocta-5,6-dienoate 
• 906542-62-9 7-methyl-2,2-diphenyl-5,6-octadien-1-ol 

Relevant academic research and scientific papers

Studies on lewis acid-mediated intramolecular cyclization reactions of allene-ene systems

The Lewis acid-mediated reactions of allene-ene compounds, derived from 3-methylcitronellal or dimethyl malonate, were carried out using various Lewis acids such as ethylaluminum dichloride, diethylaluminum chloride, titanium chloride, zinc chloride ether

Intramolecular palladium(II)-catalyzed 1,2-addition to allenes

Palladium(II)-catalyzed intramolecular 1,2-additions to allenes substituted with an internal nucleophile have been developed. Carboxylic acids, alcohols, N-substituted amides, and carbamates were used as internal nucleophiles in the palladium-catalyzed re

HOMOALLENYL RADICALS

Several homoallenyl radicals have been generated by the reaction of the corresponding iodides with Bu3SnH and found to produce small amounts of vinylcyclopropanes in addition to allene hydrocarbons establishing that homoallenyl radicals cyclize to isomeri