144367-19-1

Upstream product

• 100-51-6 benzyl alcohol 
• 125284-31-3 (1R,4R,5S,6S,7S)-4-exo-<(1'S,2'R)-1'-Hydroxy-2',3'-(isopropylidenedioxy)propyl>-6-exo,7-exo-(isopropylidenedioxy)-2,8-dioxabicyclo<3.2.1>octan-3-one 
• 144367-17-9 (-)-5-C-(Benzyloxycarbonyl)-5-deoxy-2,3:7,8-di-O-isopropylidene-α-D-erythro-L-allo-octofuranose 
• 144367-18-0 (+)-tert-Butyldimethylsilyl 5-C-(benzyloxycarbonyl)-6-O-(tert-butyldimethylsilyl)-5-deoxy-2,3:7,8-di-O-isopropylidene-α-D-erythro-L-allo-octofuranoside 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 144367-16-8 (-)-(1S,2R,6R,7R,8S,8aS)-1,2,6,7,8-Pentahydroxyindolizidine 

Relevant academic research and scientific papers

Total asymmetric syntheses of 1,5-dideoxy-1,5-iminooctitols and 1,2,6,7,8-pentahydroxyindolizidines

(1R,4R,5S,6S,7S)-4-exo-[(1'S,2'R)-1'-Hydroxy-2',3'-(isopropylidenediox y)propyl]-6-exo,7-exo-(isopropylidenedioxy)-2,8-dioxabicyclo[3.2.1]oct an-3-one ((+)-5) and its diastereomer (1S,4S,5R,6R,7R)-(1'R,2'R)-(-)-30 derived from (R)-2,3-O-isopropylideneglyc

Total syntheses of 1,5-dideoxy-1,5-imino-D-erythro-L-allo-octitol and (1S,2R,6R,7R,8S,8aS)-pentahydroxyindolizidine

The title compounds (-)-1 and (-)-2 were derived from the optically pure Diels-Alder adduct (-)-3 of furan to 1-cyanovinyl (1R')-comphanate.