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14437-03-7

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14437-03-7 Usage

Chemical Properties

Off-White Solid

Uses

N-(p-Tosyl)carbamic Acid Methyl Ester is a degradation product of Gliclazide.

Check Digit Verification of cas no

The CAS Registry Mumber 14437-03-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,4,3 and 7 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 14437-03:
(7*1)+(6*4)+(5*4)+(4*3)+(3*7)+(2*0)+(1*3)=87
87 % 10 = 7
So 14437-03-7 is a valid CAS Registry Number.
InChI:InChI=1/C9H11NO4S/c1-7-3-5-8(6-4-7)15(12,13)10-9(11)14-2/h3-6H,1-2H3,(H,10,11)

14437-03-7Relevant articles and documents

Atom-economy synthesis of N-substituted carbamate from urea derivative and dimethyl carbonate catalyzed by La/SiO2: Characterization and activity

Guo, Xiaoguanga,Shang, Jianpenga,Li, Jiana,Wang, Liguoa,Ma, Yuboa,Shi, Feng,Deng, Youquan

, p. 164 - 170 (2010)

A series of silica gel immobilized lanthanum catalysts were prepared for the atom-economy synthesis of N-substituted carbamates from urea derivatives and dimethyl carbonate. The La/SiO2 catalysts with lanthanum loadings varied from 1.3 wt% to 8.5 wt% were characterized by AES, BET, XRD, TEM, FT-IR, XPS and TPD. According to the characterization, lanthanum species with particle sizes of 5-10 nm on the surface of silica gel were formed. The catalysts were all amorphous and the surface areas were 336.5-530.2 m2/g. NH3-TPD analysis showed that all samples exhibited similar acid strength with different acid amounts. FT-IR measurement indicated that the component of lanthanum species on the catalyst surface were La(OH)3, LaOOH and hydrated La2O3. Also, the peak value of the absolute amount of LaOOH was obtained with 4.3 wt% lanthanum loading. The BET surface area decreased dramatically when the lanthanum loading was above 4.3 wt%. In consideration of the results obtained from the catalytic reactions, it could be concluded that LaOOH was the possible active species and high surface area was important for the high catalytic activity.

Alkene Syn- And Anti-Oxyamination with Malonoyl Peroxides

Curle, Jonathan M.,Perieteanu, Marina C.,Humphreys, Philip G.,Kennedy, Alan R.,Tomkinson, Nicholas C. O.

supporting information, p. 1659 - 1664 (2020/02/13)

Malonoyl peroxide 6 is an effective reagent for the syn- or anti-oxyamination of alkenes. Reaction of 6 and an alkene in the presence of O-tert-butyl-N-tosylcarbamate (R3 = CO2 tBu) leads to the anti-oxyaminated product in up to 99% yield. Use of O-methyl-N-tosyl carbamate (R3 = CO2Me) as the nitrogen nucleophile followed by treatment of the product with trifluoroacetic acid leads to the syn-oxyaminated product in up to 77% yield. Mechanisms consistent with the observed selectivities are proposed.

Microwave Promoted Transcarbamylation Reaction of Sulfonylcarbamates under Continuous-Flow Conditions

Kumpina, Ilze,Isaksson, Rebecka,S?vmarker, Jonas,Wannberg, Johan,Larhed, Mats

supporting information, p. 440 - 445 (2016/03/04)

Successful conditions for the transcarbamylation/transesterification reaction of sulfonylcarbamates with alcohols by microwave heating under continuous-flow conditions were developed. After optimization of the processes, two series of O-alkylsulfonylcarbamates were obtained in high yields and purities using microwave transparent borosilicate tube reactors. In order to also illustrate the usefulness of the protocol in a medicinal chemistry context, the methodology was used for the synthesis of three angiotensin II type 2 receptor ligands.

Sulfonyl Azides as Precursors in Ligand-Free Palladium-Catalyzed Synthesis of Sulfonyl Carbamates and Sulfonyl Ureas and Synthesis of Sulfonamides

Chow, Shiao Y.,Stevens, Marc Y.,Odell, Luke R.

, p. 2681 - 2691 (2016/04/26)

(Chemical Equation Presented). An efficient synthesis of sulfonyl carbamates and sulfonyl ureas from sulfonyl azides employing a palladium-catalyzed carbonylation protocol has been developed. Using a two-chamber system, sulfonyl azides, PdCl2, and CO gas, released ex situ from Mo(CO)6, were assembled to generate sulfonyl isocyanates in situ, and alcohols and aryl amines were exploited as nucleophiles to afford a broad range of sulfonyl carbamates and sulfonyl ureas. A protocol for the direct formation of substituted sulfonamides from sulfonyl azides and amines via nucleophilic substitution was also developed.

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