1443747-04-3Relevant articles and documents
Copper(I) complexes of mesoionic carbene: Structural characterization and catalytic hydrosilylation reactions
Hohloch, Stephan,Duecker, Fenja Leena,Van Meer, Margarethe Der,Sarkar, Biprajit
, p. 7379 - 7395 (2015)
Two series of different Cu(I)-complexes of "click" derived mesoionic carbenes are reported. Halide complexes of the type (MIC)CuI (with MIC = 1,4-(2,6-diisopropyl)-phenyl-3-methyl-1,2,3-triazol-5-ylidene (for 1b), 1-benzyl-3-methyl-4-phenyl-1,2,3-triazol-
Suzuki-Miyaura cross-coupling reaction catalyzed by PEPPSI-type 1,4-di(2,6-diisopropylphenyl)-1,2,3-triazol-5-ylidene (tzIPr) palladium complex
Huang, Jie,Hong, Jong-Tai,Hong, Soon Hyeok
, p. 6630 - 6635 (2013/01/15)
A 1,4-di(2,6-diisopropylphenyl)-1,2,3-triazol-5-ylidene (tzIPr)-based PEPPSI-type palladium complex was developed as an excellent precatalyst for the Suzuki-Miyaura cross-coupling reaction. The complex showed high activity under mild conditions for the cross-coupling reactions between various types of aryl chlorides and aryl boronic acids regardless of the steric and electronic nature of the substrates.