1444004-58-3

Basic information

• Product Name: Pt(2,2′-bipyrazine)(4-C₆H₄CF₃)₂
• Synonyms: Pt(2,2′-bipyrazine)(4-C₆H₄CF₃)₂
• CAS NO: 1444004-58-3
• Molecular Weight: 643.45
• Mol File: 1444004-58-3.mol

Chemical Properties

• CAS DataBase Reference: Pt(2,2′-bipyrazine)(4-C₆H₄CF₃)₂(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(2,2′-bipyrazine)(4-C₆H₄CF₃)₂(1444004-58-3)
• EPA Substance Registry System: Pt(2,2′-bipyrazine)(4-C₆H₄CF₃)₂(1444004-58-3)

Safety Data

• Hazardous Substances Data: 1444004-58-3(Hazardous Substances Data)

Upstream product

• 10199-00-5 2,2'-bipyrazine 
• 1444004-62-9 C₂₂H₂₈F₆PtS₂ 

Downstream Products

• 581-80-6 4,4'-bis(trifluoromethyl)biphenyl 
• 1444004-59-4 ((2,2'-bipyrazine-B(C₆F₅)₃))Pt(4-CF₃-Ph)₂ 

Relevant articles and documents

A remote lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex

A strategy for the control of electron density at a metal center is reported, which uses a remote chemical switch involving second-sphere Lewis acid binding that modulates electron density in the first coordination sphere. Binding of the Lewis acid B(C6F5)3 at remote nitrogen positions of a bipyrazine-diarylplatinum(II) complex accelerates biaryl reductive elimination by a factor of 64,000.