1444103-79-0Relevant academic research and scientific papers
A highly stable multifunctional three-dimensional microporous framework: Excellent selective sorption and visible photoluminescence
Huang, Yumei,Zheng, Xiaofang,Duan, Jingui,Liu, Wenlong,Zhou, Li,Wang, Chenggang,Wen, Lili,Zhao, Jinbo,Li, Dongfeng
, p. 6811 - 6818 (2014)
A Cd(ii)-MOF [Cd(L)(DMF)] (1) (H2L = 5-(4-pyridyl)-isophthalic acid) featuring high thermal and chemical stability has been solvothermally synthesized and characterized. Complex 1 is a robust multifunctional three-dimensional (3D) microporous framework possessing an unusual (4,5)-connected topological net. Activated 1 shows high-efficiency for the selective capture of CO2 over N2 and CH4 under ambient conditions, which ranks it among MOFs with the highest selectivity. In addition, desolvated 1 exhibits good separation ratios of H2 over N2 at lower temperature, as well as alcohols from water. In particular, desolvated 1 demonstrates significantly higher adsorption enthalpies for CO2 and CH4 gas molecules, which are in the range of the highest Qst values reported to date. Furthermore, complex 1 displays visible photoluminescence in the solid state under UV irradiation. This journal is the Partner Organisations 2014.
Syntheses, structures, and properties of CdII and Co II complexes with 5-(pyridin-4-yl)isophthalate
Hou, Chao,Zhao, Yue,Okamura, Taka-Aki,Wang, Peng,Sun, Wei-Yin
, p. 4409 - 4418 (2013/02/25)
A N-donor containing carboxylic ligand, 5-(pyridin-4-yl)isophthalic acid (H2L), was applied to construct two new coordination polymers [Cd(L)(DMF)]n (1, DMF=N,N-dimethylformamide) and {[Co(L)(H 2O)2] · 0.5CHsub
