144422-84-4

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 112069-72-4 (E)-1-amino-3-pentene-2-ol 
• 87089-12-1 (E)-2-(trimethylsilyloxy)pent-3-enenitrile 

Downstream Products

• 312521-39-4 (R)-1-t-butoxycarbonylamido-3-pentene-2-ol 
• 312521-39-4 (S)-1-t-butoxycarbonylamido-3-pentene-2-ol 
• 312521-41-8 (S)-2-acetoxy-1-t-butoxycarbonylamido-3-pentene 
• 312521-38-3 (R)-2-acetoxy-1-t-butoxycarbonylamido-3-pentene 
• 144422-90-2 E-1-dibenzylamino-4-methyl-2-penten-5-ol 
• 144422-91-3 Z-1-dibenzylamino-4-methyl-2-penten-5-ol 
• 144422-92-4 Z-1-dibenzylamino-2-pentene-4-carboxylic acid 
• 144422-89-9 E-1-dibenzylamino-3-penten-2-ol 

Relevant academic research and scientific papers

Chemoenzymatic synthesis of enantiomerically enriched aminoalkenols and glycosides thereof

1-t-Butoxycarbonylamido-3-pentene-1-ol 3 and 2-azido-4-phenyl-3-butene-1-ol 4 were enantiomerically enriched by enzymatic acetylation using various lipases and esterases (CHIRAZYM) to give acetylated compounds 5 and 7, respectively. Compound 3 gave the be

Synthesis of alkene dipeptide isosteres employing the Wittig-Still rearrangement

A new approach to the synthesis of alkene dipeptide isosteres is reported which features the use of the [2,3]-Wittig-Still rearrangement, carried out in hexanes. Employing this rearrangement alkene dipeptide isosteres of 'Gly-Xxx' are accessible starting