1444307-88-3

Basic information

• Product Name: [(P^Im)Fe^III(OH)]
• Synonyms: [(P^Im)Fe^III(OH)]
• CAS NO: 1444307-88-3
• Molecular Weight: 992.742
• Mol File: 1444307-88-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(P^Im)Fe^III(OH)](CAS DataBase Reference)
• NIST Chemistry Reference: [(P^Im)Fe^III(OH)](1444307-88-3)
• EPA Substance Registry System: [(P^Im)Fe^III(OH)](1444307-88-3)

Safety Data

• Hazardous Substances Data: 1444307-88-3(Hazardous Substances Data)

Upstream product

• 7732-18-5 water 
• 76597-79-0 3-(chloroacetyl)benzoic acid chloride 

Downstream Products

• 1444307-70-3 C₅₂H₃₀F₆FeN₆O 

Relevant articles and documents

A selective stepwise heme oxygenase model system: An iron(IV)-oxo porphyrin π-cation radical leads to a verdoheme-type compound via an isoporphyrin intermediate

The selective oxidation of the α-position of two heme-Fe III tetraarylporphryinate complexes occurs when water(hydroxide) attacks their oxidized Cmpd I-type equivalents, high-valent FeIV=O π-cation radical species ((P+?)FeIV=O). Stepwise intermediate formation occurs, as detected by UV-vis spectroscopic monitoring or mass spectrometric interrogation, being iron(III) isoporphyrins, iron(III) benzoyl-biliverdins, and the final verdoheme-like products. Heme oxygenase (HO) enzymes could proceed through heterolytic cleavage of an iron(III)-hydroperoxo intermediate to form a transient Cmpd I-type species.