144437-22-9Relevant academic research and scientific papers
Double Ci-H bond activation of C(sp3)H2 groups for the preparation of complexes with back-to-back bisimidazolinylidenes
Prades, Amparo,Poyatos, MacArena,Mata, Jose A.,Peris, Eduardo
scheme or table, p. 7666 - 7669 (2011/10/05)
Two-headed carbenes: N-heterocyclic carbene complexes of rhodium and iridium were obtained by the double Ci-H activation of CH2 groups in N heterocycles (see structure: C gray, N blue, Cl green, Ir pink). The reaction constitutes a valuable approach to new carbene ligands with unprecedented architectures. Copyright
Polyazapolycyclics by Condensation of Aldehydes with Amines. 3. Formation of 2,4,6,8-Tetrabenzyl-2,4,6,8-tetraazabicyclooctanes from Formaldehyde, Glyoxal, and Benzylamines
Nielsen, Arnold T.,Nissan, Robin A.,Chafin, Andrew P.,Gilardi, Richard D.,George, Clifford F.
, p. 6756 - 6759 (2007/10/02)
The condensation of formaldehyde, glyoxal, and benzylamine, in a stoichiometric ratio, leads to 2,4,6,8-tetrabenzyl-2,4,6,8-tetraazabicyclooctane (1d) in methanol solvent with formic acid catalyst.Six phenyl-sbstituted derivatives of 1d, as well as
